Core Overview
Methylcyclohexanediamine (abbreviated as HTDA or MCHDA) is a high-performance alicyclic diamine epoxy resin curing agent. With its unique molecular structure (cyclohexane backbone + methyl group), it achieves an excellent balance between high rigidity and toughness, and is regarded as a strategic material choice for breaking through the performance limitations of epoxy resin systems and developing high-end competitive products.
Core Performance Advantages
1. High Rigidity & High Heat Resistance
• Reason: Its molecular core is a rigid cyclohexane backbone.
• Result: It provides the cured product with excellent thermal stability, high glass transition temperature (Tg), creep resistance and dimensional stability, making it suitable for high-temperature and heavy-load environments.
2. Excellent Toughness
• Reason: The methyl group in the molecule introduces steric hindrance and optimizes the flexibility of molecular chain segments.
• Result: It effectively overcomes the brittleness of traditional alicyclic amines such as IPDA and significantly improves impact resistance.
3. Excellent Weather Resistance
• Reason: The molecular structure contains no benzene ring and is a saturated alicyclic structure.
• Result: It fundamentally avoids oxidative yellowing under ultraviolet irradiation. The cured product does not yellow under UV exposure and maintains stable color at high temperature, making it especially suitable for outdoor coatings, topcoats and other applications with strict appearance requirements.
4. Process Friendliness
• Low viscosity: It has good wetting performance in epoxy resin systems, which is beneficial for mixing, defoaming and filling complex shapes.
• Low volatility and environmental safety: As a larger-molecule curing agent, HTDA has low vapor pressure and low volatility, with less odor in the production environment and significantly reduced health hazards to operators, meeting modern environmental standards.
Physicochemical Properties
|
Property |
Typical Value |
|
Appearance |
Colorless to pale yellow transparent liquid |
|
Color (Hazen) |
≤40 |
|
Odor |
Slight ammonia odor |
|
Viscosity |
5-15 mPa·s/25°C |
|
Water Content (ppm) |
≤1000 |
|
Amine Value |
820-880 mg KOH/g |
|
Density |
≈0.94 g/mm3 |
|
Freezing Point |
-92°C |
|
Boiling Point |
≈208°C |
|
Active Hydrogen Equivalent (AHEW) |
≈32 g/eq |
|
Molecular Formula |
C₇H₁₆N₂ |
|
Molecular Weight |
128.22 |
|
Isomers |
Exists as multiple isomers such as cis and trans; differences in spatial structure affect reactivity and application performance. |
|
Miscibility |
Good miscibility with organic solvents such as alcohols and ethers. |
|
Safety |
The product has certain toxicity. Professional protective equipment is required during operation, and safety procedures should be strictly followed. |
Storage Notes
Store in a cool and ventilated warehouse. The storage temperature should not exceed 40°C. It should be stored separately from oxidants and edible chemicals, and mixed storage is strictly prohibited. Suitable container materials include glass and high-density polyethylene. Keep the container tightly closed. Keep away from fire and heat sources. The warehouse must be equipped with lightning protection devices. The exhaust system should be equipped with grounding devices for static electricity discharge. Explosion-proof lighting and ventilation should be used. Equipment and tools that may generate sparks are prohibited. The storage area should be equipped with leakage emergency treatment equipment and suitable containment materials.
Main Application Fields
|
Application Field |
Core Application Scenario |
Key Performance Support |
|
High-performance composites |
Wind turbine blades, aerospace components, high-end sports equipment (bicycle frames, rackets) |
High Tg, excellent fatigue strength, good toughness, environmental aging resistance |
|
Electronic and electrical field |
Chip encapsulation (Underfill/Glob Top), transformer casting, high-voltage insulators |
Excellent electrical insulation, low dielectric loss, low curing stress, resistance to high and low temperature and high humidity |
|
Anti-corrosion coatings |
Offshore platforms, chemical storage tanks, pipeline inner walls, high-end decorative topcoats, automotive clear coats |
Dense cross-linked network, chemical corrosion resistance, excellent weather resistance, gloss and color retention |
|
Structural adhesives |
Building structural reinforcement, automotive structural bonding, aerospace assembly |
High shear and peel strength, excellent durability |
|
Industrial flooring |
Factory workshops, warehouse wear-resistant floors, pharmaceutical plant anti-corrosion floors |
Mechanical wear resistance, heavy-load impact resistance, chemical corrosion resistance |
Performance data
The curing time at room temperature for 100:16 (128 resin) is 1 hour and 55 minutes.
|
Component |
Count the number of portions by weight |
||
|
Standard epoxy resin based on double A (EEW = 185 g/eq) |
100 |
||
|
HTDA (AHEW = 33 g/eq) |
18 |
||
|
Hybrid characteristics |
Test data |
Test method |
|
|
The viscosity of the mixture at 23°C |
1300 mPa·s |
DIN EN ISO 3219 |
|
|
The operating time at 23°C |
69 min |
DIN 16945 |
|
|
The time to reach 6 Pa·s at 23°C |
131 min |
DIN 16945 |
|
|
The time to reach 6 Pa·s at 45°C |
69 min |
DIN 16945 |
|
|
The time to reach 6 Pa·s at 75°C |
17 min |
DIN 16945 |
|
|
Gel time (70°C) |
51 min |
ASTM D4473 |
|
|
Gel time (90°C) |
25 min |
ASTM D4473 |
|
|
Gel time (110°C) |
7 min |
ASTM D4473 |
|
Curing procedures: 2h-80°C, 2h-100°C, 2h-100°C, 2h-120°C, 2h-140°C, 2h-160°C.
Mechanical properties
|
Mechanical properties |
Unit of value |
Test method |
|
Tg |
75°C |
DSC, mod., 5 K/min |
|
Thermal deformation (HDT) |
73°C |
DIN EN ISO 75-2 |
|
Tensile strength |
53 MPa |
DIN EN ISO 527-2 |
|
Tensile modulus |
2391 MPa |
DIN EN ISO 527-2 |
|
The maximum tensile elongation |
4.9% |
DIN EN ISO 527-2 |
|
Bending strength |
86 MPa |
DIN EN ISO 178 |
|
Bending modulus |
2487 MPa |
DIN EN ISO 178 |
|
Simply supported beam (impact strength) |
73 kJ/m² |
DIN EN ISO 179-1 |
Core Value of Choosing HTDA
When your application faces challenges such as high temperature, heavy load, strong corrosion, long service life or strict appearance requirements, HTDA is regarded as a key material to open the door to high-performance epoxy systems. It perfectly combines the high-strength advantages of traditional alicyclic amines with significantly improved toughness, weather resistance and process friendliness, helping your products establish a solid performance foundation in intense market competition.
Summary
Methylcyclohexanediamine (HTDA) is a specialty curing agent designed for high-performance applications. It effectively solves the contradiction of traditional alicyclic amines, namely high rigidity but high brittleness. With outstanding comprehensive performance, it is one of the preferred high-end materials for epoxy formulators pursuing high heat resistance, high strength, high toughness, high weather resistance and environmental friendliness.